
| Title | Intensities and asymmetries of electronic Raman scattering in Thulium and Erbium phosphate |
| Publication Type | Journal Article |
| Year of Publication | 1985 |
| Authors | Becker, P. C., Norman E. Edelstein, G. M. Williams, Jerome J. Bucher, Richard E. Russo, J. Arnold Koningstein, Lynn A. Boatner, and Marvin M. Abraham |
| Secondary Title | Physics Review B |
| Volume | 31 |
| Issue | 12 |
| Section | 8102 |
| Pagination | 8102-8110 |
| Date Published | 06/1985 |
| Publication Language | eng |
| Keywords | intensities, intensity, raman, raman scattering, raman-scattering, scattering |
| Abstract | An investigation of the low-temperature electronic Raman scattering spectra of ErPO4 and TmPO4 has been carried out. The experimental intensities have been compared with the standard second-order theory of two-photon processes for both intermultiplet and intramultiplet transitions between individual crystal-field levels. Adequate agreement is found in the case of ErPO4, but serious discrepancies exist for TmPO4. It is shown that electronic Raman scattering is a sensitive technique for testing the Judd-Ofelt–type theories of two-photon processes in rare-earth crystals. Strong asymmetry, a characteristic feature of electronic Raman scattering, has been observed in several of the transitions. |
| Notes | NOT IN FILE |
| URL | http://link.aps.org/doi/10.1103/PhysRevB.31.8102 |
| DOI | 10.1103/PhysRevB.31.8102 |
| Citation Key | 14198 |