Refractive Index Changes of Pd-Coated Magnesium Ianthanide Switchable Mirrors Upon Hydrogen Insertion

TitleRefractive Index Changes of Pd-Coated Magnesium Ianthanide Switchable Mirrors Upon Hydrogen Insertion
Publication TypeJournal Article
Year of Publication1999
Authorsvon Rottkay, Klaus, Michael D. Rubin, and Peter A. Duine
Secondary TitleJournal of Applied Physics
Volume85
Number1
Pagination408-413
Publication Languageeng
Call NumberLBNL-41976
Abstract

The optical effect upon insertion of hydrogen into Pd-coated magnesium lanthanide switchable mirrors is investigated in terms of the changes of their complex refractive indices. A significant change in the optical constants of LnMg layers is seen between the as-deposited state and the dehydrided state after one cycle. Furthermore, the optical effect of switching the Pd cap layer to a PdH cap layer was determined. It is shown that the Pd layer mainly limits the visible transmittance of the hydrided stack to about 35%-40%. Whereas the extinction coefficient of dehydrided LnMg layers at 550 nm is between 2.2 and 3.1, it is as low 10-4 as in the transparent state. This is of great promise to applications requiring large optical contrast (e.g., optical switches).

Custom 1

Windows and Daylighting Group

LBNL Report NumberLBNL-41976
Citation Key12213
AttachmentSize
PDF396.85 KB