New Spectroscopic Technique Reveals the Dynamics of Operating Battery Electrodes

January 29, 2014

The following story appears on the website of Berkeley Lab's Advanced Light Source. Three of the scientists involved in this research are based in Berkeley Lab's Environmental Energy Technologies Division.

Developing high-performance batteries relies on material breakthroughs. During the past few years, various in situ characterization tools have been developed and have become indispensable in studying and the eventual optimization of battery materials. However, soft x-ray spectroscopy, one of the most sensitive probes of electronic states, has been mainly limited to ex situ experiments for battery research.

Recent ALS work could change this trend. Researchers have developed a new technique based on soft x-ray spectroscopy that could help scientists better understand and improve the materials required for high-performance lithium-ion batteries. The technique measures something never seen before: the migration of ions and electrons in an integrated, operating battery electrode.

Over the past few years, scientists have developed several ways to study the changes in a working electrode. These include techniques based on hard x-rays, electron microscopy, neutron scattering, and nuclear magnetic resonance imaging. But most of these methods track structural changes. They don't track electron and ion dynamics directly, which is very important in the push to understand and optimize battery performance.

Read the rest at the link below.